Excellent sodium ion conductivity and air stability of manganese-substituted Na 3 SbS 4 solid electrolytes

Z Gong, L Shu, J Yin, C Gao, Y Liu, X Zhou… - Journal of Materials …, 2023 - pubs.rsc.org
… −1 when using nontoxic and economical elements. For the first … optimized the lithium superionic
conductor Li 10 SiP 2 S 11.3 … were improved via component design and process control. …

Solvent-free and low temperature synthesis of chalcogenide Na superionic conductors for solid-state batteries

S Halacoglu, Y Li, W Arnold, V Shreyas, X Guo… - Chemical Engineering …, 2023 - Elsevier
… systems from an economic perspective [5], [6], [7], [8], [9]. Na … A thermal decomposition
process is the most straightforward … potential phase stability plot of Na 3 SbS 4 is consistent with …

Abnormally Low Activation Energy in Cubic Na3SbS4 Superionic Conductors

Q Zhang, C Zhang, ZD Hood, M Chi, C Liang… - Chemistry of …, 2020 - ACS Publications
… Much research detailing Na 3 SbS 4 focused on its synthetic approaches and interfacial
stability … The distinct jump process clearly indicates that the diffusion mechanism is different for t-…

Exceptionally high sodium ion conductivity and enhanced air stability in Na3SbS4 via germanium doping

L Yu, Q Jiao, B Liang, H Shan, C Lin, C Gao… - Journal of Alloys and …, 2022 - Elsevier
… solid-state chemical reaction utilizing the economical Na 2 S·9H 2 … sulfide superionic
conductors with high ionic conductivity at … have been made on improving the conductivity of …

Airstable, flexible Na3SbS4 thin membrane prepared via a dry‐film strategy

C He, C Gao, J Zhang, X Li, T Zhou… - Journal of the …, 2024 - Wiley Online Library
… Sahu, AS Pandian, JK Keum, et al., An airstable Na3SbS4 superionic conductor prepared
by a rapid and economic synthetic procedure. Angewandte Chemie, (2016); 128, 8693-8697. …

Zn doping for enhanced sodium-ion conductivity and air stability in Na3SbS4 solid electrolyte

Y Fu, Z Gong, D Li, Y Liu, X Zhou, Y Yang… - Journal of Materials …, 2024 - Springer
synthesis of these materials presented challenges, as it necessitates stringent conditions. For
instance, the annealing process … , in line with superionic conductors described in previous …

Visualization of Solid‐State Synthesis for Chalcogenide Na Superionic Conductors by in‐situ Neutron Diffraction

S Halacoglu, S Chertmanova, Y Chen, Y Li… - …, 2021 - Wiley Online Library
… (Na) sources are more economic meanwhile, metallic Na also … synthesis process of Na 3
SbS 4 and Na 3 SbS 3.5 Se 0.5 … –305 C; then cubic structured Na 3 SbS 4 is stable up to 590 C …

Physical and electrochemical behavior of affordable Na3SbS4 solid electrolyte at different heat treatment temperatures

B Liang, L Yu, G Wang, C Lin, C Gao, X Shen… - Ceramics …, 2022 - Elsevier
… A Na 3 SbS 4 superionic conductor was prepared with a safe and economical synthesis … ,
a decrease in activation energy, and enhanced air stability, which was largely due to the high …

High ionic conductivity and stable phase Na11. 5Sn2Sb0. 5Ti0. 5S12 for all-solid-state sodium batteries

W Weng, G Liu, L Shen, X Yao - Journal of Power Sources, 2021 - Elsevier
… P-based materials and suffer from poor air stability [22,24,25]. … Na 3 SbS 4 was developed
with higher ionic conductivity … or kinetically stable at room temperature under our synthetic

Preparation and Characterization of Cation-Substituted Na3SbS4 Solid Electrolytes

F Tsuji, N Masuzawa, A Sakuda… - ACS Applied Energy …, 2020 - ACS Publications
… electrolyte is known to show a high sodium-ion conductivity … both high ionic conductivity and
high stability against hydrolysis. … It is noted that mechanochemical synthesis is the key to the …